Multiblock Copolymers and Colloidal Stability
β Scribed by Christopher M. Wijmans; Frans A.M. Leermakers; Gerard J. Fleer
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 606 KB
- Volume
- 167
- Category
- Article
- ISSN
- 0021-9797
No coin nor oath required. For personal study only.
β¦ Synopsis
Block copolymers that have both adsorbing and nonadsorbing blocks can be used to stabilize colloidal dispersions. However, they can also induce an attraction between two particles by forming bridges between the surfaces. In this paper we investigate when such an attraction occurs and how its magnitude depends on the relevant system parameters. Most attention is paid to cend-adsorbed triblock ( (\Lambda-\mathbf{B}-\Lambda) ) copolymers and a few calculittions are presented for polymers consisting of a larger number of blocks (\left((\Lambda-B)_{n}-\Lambda\right.) with (\left.n>1\right)). Adsorbed layers of triblock copolymers with identical adsorbing groups always cause an attractive part in the two-particle interaction curves. Adsorbed layers of multiblock ( (n>1) ) copolymers with long blocks behave similar to triblock copolymers. When their blocks become very short, these multiblock copolymers resemble homopolymers whose interaction parameters have some average value of those for both types of blocks. 1994 Academic Press. Inc.
π SIMILAR VOLUMES
The use of multiblock copolymers for the compatibilization of immiscible polymer blends is controversially discussed in the literature. Investigations have been carried out to estimate the effect of multiblock copolymers containing segments of a liquid crystalline polyester (LCP) and polysulfone (PS
## Abstract **Summary:** Anionic polymerization has proven especially useful for the precise construction of multiblock copolymers with controlled compositions and narrow molecular weight distributions. The block copolymer sequences which can be easily prepared are however largely restricted by the
## Abstract An algorithm was developed to generate an ensemble of statistical multiblock AB copolymer chains via a polymerβanalogous reaction with acceleration. Ordering in the cylindrical ensemble of such chains is simulated via successive rotation of chains until an arrangement with the maximum e
We use dynamic light scattering to measure the time-dependent increase of the average hydrodynamic radius of colloidal silica particles in the presence of salt. This increase appears to be linear in time up to twice the radius of unaggregated particles. The method is a very useful tool in monitoring