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On the Ordering of Statistical Multiblock Copolymers

✍ Scribed by Arkadiy D. Litmanovich; Vadim V. Podbelskiy; Yaroslav V. Kudryavtsev

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
325 KB
Volume
19
Category
Article
ISSN
1022-1344

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✦ Synopsis

Abstract

An algorithm was developed to generate an ensemble of statistical multiblock AB copolymer chains via a polymer‐analogous reaction with acceleration. Ordering in the cylindrical ensemble of such chains is simulated via successive rotation of chains until an arrangement with the maximum energy of attraction between each two nearest chains is attained. The master relation of the ordering and the relations between AA, BB and AB contact fractions were found. Those relations permit to estimate the adequacy of modeling polymers of finite length. Influence of a chain structure, length, and interchain interactions on the ordering efficiency was studied.
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