Multi-dimensional crystal engineering of metal complexes based on complementary hydrogen bonding
โ Scribed by Andrew Houlton; D. Michael; P. Mingos; David J. Williams
- Book ID
- 105024566
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 372 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
In the field of crystal engineering, many attempts have been made to control the molecular arrangements in crystal by simultaneous use of coordination bonds of a transition metal ion and complementary intermolecular hydrogen bonds. We obtained the first crystal structure of the hydrogen bonded metal
## Abstract Novel triply hydrogen bonded suprastructures based on [M(tdpd)~2~(L)~2~]^2โ^ (H~2~tdpd=1,4,5,6โtetrahydroโ5,6โdioxoโ2,3โpyrazinedicarbonitrile, L=solvent) and melamineโanalogous cations have been synthesized and characterized. The use of anions containing two AAA sets from [M(tdpd)~2~(L