In the field of crystal engineering, many attempts have been made to control the molecular arrangements in crystal by simultaneous use of coordination bonds of a transition metal ion and complementary intermolecular hydrogen bonds. We obtained the first crystal structure of the hydrogen bonded metal
โฆ LIBER โฆ
Crystal Engineering on Controlled Crystal Arrays Using Hydrogen Bonding Biimidazolate Metal Complexes
โ Scribed by Makoto Tadokoro
- Book ID
- 101962643
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 10 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Novel triply hydrogen bonded suprastructures based on [M(tdpd)~2~(L)~2~]^2โ^ (H~2~tdpd=1,4,5,6โtetrahydroโ5,6โdioxoโ2,3โpyrazinedicarbonitrile, L=solvent) and melamineโanalogous cations have been synthesized and characterized. The use of anions containing two AAA sets from [M(tdpd)~2~(L
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