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MPP+ Redox Cycling: A New Mechanism Involving Hydride Transfer

✍ Scribed by JAMES D. ADAMS; LORI K. KLAIDMAN; ENRIQUE CADENAS


Book ID
119867097
Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
98 KB
Volume
648
Category
Article
ISSN
0890-6564

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A new mechanistic model for hydride tran
✍ H.M. Buck πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 376 KB

## Abstract A mechanistic study of hydride transfer based on (simplified) NADH/NAD^+^ model systems is given. The new model originates from a classical mechanism generally indicated as being an intramolecular nucleophilic displacement reaction. There is some controversy with the results of quantum‐