Motional Heterogeneity of Intercalated Species in Modified Clays and Poly(ε-caprolactone)/Clay Nanocomposites
✍ Scribed by Urbanczyk, L.; Hrobarikova, J.; Calberg, C.; Jérôme, R.; Grandjean, J.
- Book ID
- 127251688
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 69 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0743-7463
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A novel segmented polyurethane/clay (PU/clay) nanocomposite based on poly(caprolactone), diphenylmethane diisocyanate, butanediol, and poly(caprolactone)/ clay prepolymer was synthesized as evidenced by FTIR and X-ray diffraction studies. Poly(caprolactone)/clay (PCL/clay) prepolymer was first synth
## Abstract PCL/clay nanocomposites were prepared by microwave‐assisted in situ ROP of __ε__‐caprolactone in the presence of either unmodified clay (Cloisite® Na^+^) or clay modified by quaternary ammonium cations containing hydroxyl groups (Cloisite 30B). This PCL showed significantly improved mon