Motifs of Closest Packings: The Compounds Zn3(PS4)2 and LiZnPS4.
β Scribed by Stefan Joergens; Dirk Johrendt; Albrecht Mewis
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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The solution-mediated syntheses and single-crystal structures of (CN 3 H 6 ) 2 ' Zn 3 (HPO 3 ) 4 ' H 2 O (I) and H 3 N(CH 2 ) 3 NH 3 ' Zn 3 (HPO 3 ) 4 ' H 2 O (II) are reported. These phases contain networks of vertex-sharing ZnO 4 tetrahedra and HPO 3 pseudopyramids accompanied by organic cations a