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Morphology dependence of the triplet excited state formation and absorption in polyfluorene

✍ Scribed by Hayer, Anna; Khan, Amena L. T.; Friend, Richard H.; Köhler, Anna

Book ID
120236947
Publisher
The American Physical Society
Year
2005
Tongue
English
Weight
45 KB
Volume
71
Category
Article
ISSN
1098-0121

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The first excited triplet state of dimesitylcarbene has been generated in solution at room temperature. It has a lifetime of 60 ns and shows fluorescence with A mp~ = 501 nm and absorption with A,,. = 360 nm. This species is quenched by oxygen and carbon tetrachloride with rate constants of (4.4kO.8