Monte Carlo and molecular orbital study of the (CH3)2NO radical in solution
β Scribed by Hideto Takase; Osamu Kikuchi
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 540 KB
- Volume
- 181
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
The hinetics of the reactions of the (CI13)2K rrtduxl wthX0.N02,and O2 rrere studied usins FTIR spectroscopy. The tutwe of the products and the ratio ofr.~tc constants for these reactions acre dctermmed\_ The results were used to evalu.rte the potenti.n for nitros.unine .md nitramine formation in X0
Alkyl and alkylperoxy radicals originating from dimethyl ether have been studied in the gas phase at 296 K. A pulse radiolysis-UV absorption technique was used. Absorption cross-sections were quantified over the wavelength range 220-350 nm. At 230 nm, O'cH3oclJ2 = (4.2 + 0.5)Γ 10 -18 cm 2 molecule-l