Addition of p-tert-butylcalix[4]arene LH 4 to the dinuclear ported by two bridging Β΅ 2 -ΞΊ 2 O,ΞΊ 2 O-calix[4]arene ligands in compounds M 2 (NMe 2 ) 6 (M = Mo, W) results in the formation the solid state. These compounds are the first examples of a of [NH 2 Me 2 ] 2 [L 2 M 2 ] 1 (M = Mo) and 2 (M = W
β¦ LIBER β¦
Mononuclear tungsten(VI) calix[4]arene complexes
β Scribed by Corazza, Fabio.; Floriani, Carlo.; Chiesi-Villa, Angiola.; Rizzoli, Corrado.
- Book ID
- 126838607
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 481 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0020-1669
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Syntheses, spectroscopic properties, molecular structures, and LW(NMes)(NCMe) 2b(NCMe) are reported. All complexes contain a group VI metal imido [M=NR] moiety and bonding of novel calix[4]arene imido compounds are described. Treatment of M(NtBu) 2 (NHtBu) 2 Ia (M = Mo), Ib mounted on the phenoxide