Syntheses, spectroscopic properties, molecular structures, and LW(NMes)(NCMe) 2b(NCMe) are reported. All complexes contain a group VI metal imido [M=NR] moiety and bonding of novel calix[4]arene imido compounds are described. Treatment of M(NtBu) 2 (NHtBu) 2 Ia (M = Mo), Ib mounted on the phenoxide
β¦ LIBER β¦
Syntheses and Molecular Structures of New Calix[4]arene Molybdenum and Tungsten Complexes
β Scribed by Juri Attner; Udo Radius
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 186 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0947-6539
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## Abstract We present the synthesis and characterization of disilaβ and distanna __ansa__ halfβsandwich complexes of Groupβ 6 transition metals. These compounds exhibit high ring strain within the __ansa__ bridge, which is the key factor for the insertion of elemental chalcogens.