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Mononuclear and dinuclear copper(I) complexes with a particularly bulky phosphine ligand. Unusual synthesis and crystal structure characterizations

✍ Scribed by Anne Marie Larsonneur-Galibert; Paule Castan; Joël Jaud; Gérald Bernardinelli


Publisher
Springer
Year
1996
Tongue
English
Weight
478 KB
Volume
21
Category
Article
ISSN
0340-4285

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The reaction of CuC1 or CuX 2 (X = C1 or NO3) with NPm (diphenylphosphinodiphenylaminomethane) yields molecular P-bonded copper(I) complexes of general formula CuL2X. These complexes are isostructural. For both complexes the coordination geometry around the copper atom is almost trigonal planar and