๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Monomolecular and collision-induced predissociation in the mass spectrum of DBr

โœ Scribed by G. Mathieu; H. Wankenne; J. Momigny

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
323 KB
Volume
17
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

A new prcdissociation process is obsewzd in the mass spectrum of DBr. The stable predissociated electronic state is crossed by the Franck-Condon region around 17 eV; its radiative lifetime must be of the order of IO6 sec. This state can only he derived from an electronic contiguration differing by more than one molrcular orbital fmm that of the ground state of the molecule.

๐Ÿ“œ SIMILAR VOLUMES

Monomolecular and collision induced proc
Monomolecular and collision induced processes for the appearance of metastable diatomic ions
โœ H. Wankenne; J. Momigny ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 301 KB

It is shown mass spectrometrically that monqmolecular metastabie transition processes are observed for the reactions Ni -N+ + lU and CO+-C + O+: the first of these processes is also observed as resulting from a collision induced reaction of about 10 times shorter lifetime than the monomolecular one:

Collision- and non-collision-induced pre
Collision- and non-collision-induced predissociation in the appearance of S+ and CS+ ions from CS2 under electron impact
โœ J. Momigny; G. Mathieu; H. Wankenne; M.A.A. Ferreira ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 404 KB

Metastnble transitions in CS$ leading to S' + CS and CS++ S under electron impact on CS2 are reported. The predissociation processes able to explain the occurrence of these metastablc transitions are discussed. An interpretation of mrne fast dissociation processes is suggested.