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Monomethylation of aromatic amines via sodium borohydride mediated carbon-nitrogen bond cleavage

✍ Scribed by Kadin, Saul B.

Book ID
118026547
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
428 KB
Volume
38
Category
Article
ISSN
0022-3263

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Stereospecific synthesis of carbocyclic
Stereospecific synthesis of carbocyclic nucleosides from 2-azabicyclo-[2.2.1]heptan-3-ones via sodium borohydride mediated carbon-nitrogen bond cleavage
✍ Nobuya Katagiri; Makoto Muto; Chikara Kaneko 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 245 KB

New synthons for carbocyclic nucleosides have been synthesized from 2-azabicyclo[2.2.l]hept-5-en-3-one readily available from cyclopentadiene, through introduction of an electron-withdrawing substituent at the 2-position followed by reduction with sodium borohydride. Previously, we have synthesized