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Monomer reactivities in radiation-induced graft copolymerization. Part II. Graft copolymerization to Teflon

✍ Scribed by Odian, George ;Acker, Terese ;Rossi, Albert ;Ratchik, Elliot

Publisher
John Wiley and Sons
Year
1962
Weight
391 KB
Volume
57
Category
Article
ISSN
0022-3832

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✦ Synopsis

Abstract

The gamma radiation‐induced surface graft copolymerizations of styrene—acrylonitrile and styrene—methyl acrylate to Teflon were studied. It was observed that the compositions of the various grafted copolymers are richer in the more polar monomer than one would predict from the Lewis‐Mayo copolymer composition equation. These results were interpreted in terms of a preferential solvation of the relatively immobile growing graft polymer free radicals by the polar monomers.

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