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Monohydrazido(2-)-complexes of molybdenum and tungsten (IV), (V) and (VI)

✍ Scribed by Jonathan R. Dilworth; Stephen Morton

Publisher
Springer
Year
1987
Tongue
English
Weight
210 KB
Volume
12
Category
Article
ISSN
0340-4285

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## Abstract WF~6~ reacts with phosphines R~3~P forming 1:1 compounds. With R=P(CH~3~)~3~ the coordination around the tungsten atom is capped trigonal prismatic, with R=P(CH~3~)~2~C~6~H~5~ the coordination is capped octahedral, as established by single‐crystal structure determinations: [(CH~3~)~3~Pο£Ώ