Isothiocyanate complexes of molybdenum (VI) and tungsten (VI)
β Scribed by Brian J. Brisdon; Dennis A. Edwards
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 103 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0020-1650
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## Abstract WF~6~ reacts with phosphines R~3~P forming 1:1 compounds. With R=P(CH~3~)~3~ the coordination around the tungsten atom is capped trigonal prismatic, with R=P(CH~3~)~2~C~6~H~5~ the coordination is capped octahedral, as established by singleβcrystal structure determinations: [(CH~3~)~3~Pο£Ώ
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