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Monoalkylboranes from Alkylidene(triphenyl)phosphoranes and Borane; Combination of Ylide Reactions and Hydroboration

✍ Scribed by Prof. Dr. Hans Jüirgen Bestmann; Dipl.-Chem. Kurt Sühs; Dipl.-Chem. Thomas Röder


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
207 KB
Volume
20
Category
Article
ISSN
0044-8249

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4-(4-Methylphenyl)-2,3-benzoxazin-1-one (1) reacts thermally with a series of alkylidene phosphoranes and the relevant salts to give mainly substituted isoquinolines. Thus, compound 1 reacts with ester ylides 2a and 2b to give isoquinolones 7a and 7b, whereas with benzoylmethylenetriphenylphosphoran