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ChemInform Abstract: Study of Insertion Reactions with Phosphorus Ylides — On Reactions Between 4-(4-Methylphenyl)-2,3-benzoxazin-1-one and Alkylidene Phosphoranes.

✍ Scribed by Wafaa Mahmoud Abdou; Amin Farouk Mohammed Fahmy; Azza Abdel-Azeem Kamel

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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4-(4-Methylphenyl)-2,3-benzoxazin-1-one (1) reacts thermally with a series of alkylidene phosphoranes and the relevant salts to give mainly substituted isoquinolines. Thus, compound 1 reacts with ester ylides 2a and 2b to give isoquinolones 7a and 7b, whereas with benzoylmethylenetriphenylphosphoran

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