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Mono and trinuclear lanthanide complexes of 13-membered tetraaza macrocycle: Synthesis and characterization

✍ Scribed by B Singh; V L Singh

Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1999
Tongue
English
Weight
680 KB
Volume
111
Category
Article
ISSN
0253-4134

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Metal phthalocyanines (M = Cu, Ni, Co, SnCI2) 3-6 containing four 14-membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni2+ ions giving a pentanuclear com-plex which is extremely soluble in polar solvents. The mass spectrum