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Mono- and homobinuclear dioxouranium(VI) complexes of various compartmental ligands.

✍ Scribed by Richard C. Coombes; David E. Fenton; P. Alessandro Vigato; Umberto Casellato; Maurizio Vidali

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
202 KB
Volume
54
Category
Article
ISSN
0020-1693

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✦ Synopsis

Compartmental ligands are defined as having two adjacent, dissimilar coordination sets for metal complexation [I]. The reaction of an cu,o-diamine with one terminal keto-function of a fltriketone, or flketophenol, leads to the formation of compartmental ligands in which one site contains an -NzOz donor set, and the other site an -0202 donor set.

πŸ“œ SIMILAR VOLUMES

Actinide and lanthanide complexes with b
Actinide and lanthanide complexes with bidentate ligands. Crystal structure of methanolbis(N-phenylbenzoylhydroxomato)dioxouranium(VI)
✍ U. Casellato; P.A. Vigato; S. Tamburini; R. Graziani; M. Vidali πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 279 KB

Th(NCS)4\*4dmpa (2) (ThCs4HMNs04S4) M = 821 .O, monoclinic P, = 22.759(6), b = 13.763(4), c = 11.910&%: fi = 91.4(l)", Z = 4 A(MoK,-J 0.71069 A. 3729 reflections with I $ 2.50(l) used in the structure solution and refinement, R = 0.049, R, = 0.053. The coordination geometry for (I) is pentagonal b