Compartmental ligands are defined as having two adjacent, dissimilar coordination sets for metal complexation [I]. The reaction of an cu,o-diamine with one terminal keto-function of a fltriketone, or flketophenol, leads to the formation of compartmental ligands in which one site contains an -NzOz do
Dioxouranium(VI) complexes of aliphatic (mono- and di-) hydrazone-oximes
✍ Scribed by Aïcha Yacouta-Nour; Abobaker K. T. Maki; Monsen M. Mostafa; Kamal M. Ibrahim; Ashraf A. El-Bindary
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 486 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0340-4285
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The reaction between uranyl acetate dihydrate and some mono-and dioxime ligands in absolute ethanol and in the presence and/or absence of sodium acetate is reported. The structures of the isolated dioxouranium (VI) complexes as well as the existence of dihydroxo bridge structures are characterized b
¨Ä bstract Ž . Ž . Olefin epoxidation by Mo VI peroxo complexes was computationally investigated DFT B3LYP for various monoper-Ž .Ž .Ž . Ž . oxo models X MoO O H O NH with anionic ligands X and for the experimentally known complex MoO O 2 2 2 3 2 Ž .Ž . dipic H O . All these monoperoxo complexes exh