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Molybdenum tetracarbonyl complexes with functionalised aminophosphine ligands: cis-[Mo(CO)4(PPh2NHR)2] (R=Ph, But) — molecular structures of PMes2NHPh (Mes=2,4,6-Me3C6H2), PPh2NHBut and cis-[Mo(CO)4(PPh2NHBut)2]

✍ Scribed by Olaf Kühl; Steffen Blaurock; Joachim Sieler; Evamarie Hey-Hawkins


Book ID
108427985
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
160 KB
Volume
20
Category
Article
ISSN
0277-5387

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Metallacrown ethers with trans-tetracarb
✍ Christina H Duffey; Charles H Lake; Gary M Gray 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 263 KB

Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac