Molybdenum-Mediated Carbonylation of Aryl Halides with Nucleophiles Using Microwave Irradiation
โ Scribed by Roberts, Bryan; Liptrot, David; Alcaraz, Lilian; Luker, Tim; Stocks, Michael J.
- Book ID
- 120364984
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 235 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1523-7060
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๐ SIMILAR VOLUMES
Mo(CO) 6 acts as a source of carbon monoxide for the palladium-catalysed, microwave-assisted, carbonylative coupling of aryl or heteroaryl halides with sulfamide nucleophiles to yield aryl and heteroaryl acyl sulfamides.
Palladium-catalyzed aminocarbonylations of various (hetero)aryl halides with allylamine using Mo(CO) 6 as a solid, in situ CO source, were explored. Microwave-enhanced conditions proved to be highly useful in promoting the conversions in a mere 10-20 min with various (hetero)aryl iodides, bromides a