Molybdenum incorporated silicalite as catalyst for epoxidation of olefins
β Scribed by M Masteri-Farahani; F Farzaneh; M Ghandi
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 223 KB
- Volume
- 192
- Category
- Article
- ISSN
- 1381-1169
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π SIMILAR VOLUMES
Catalytic properties of dimeric molybdenum(VI) triketonates were compared to those of MoO,(acac), in the epoxidation reaction of cyclooctene and 1,5cyclooctadiene with tertiary butyl hydroperoxide. Studies of the reaction at a molar ratio of olefin:TBHP:catalyst = l:l:O.OOl for the monoolefin and 1:
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Continuous epoxidation of propylene with 30-wt% hydrogen peroxide in isopropyl alcohol solvent over titanium silicalite (TS-1) zeolite was carried out and the good selectivity to propylene oxide and stability of TS-1 were obtained. After the reaction of 263 h, the deactivation of the TS-1 catalyst o