ALTHOUGH the electrochemical evolution of hydrogen on graphite in bisulphate melts has been studied under a limited range of experimental conditions,l no data have been reported about the anodic oxidation of hydrogen in molten electrolytes. An investigation of these reactions was attempted by employ
✦ LIBER ✦
Molten salt electrolysis—II hydrogen overpotential on platinum and gold in molten KHSO4
✍ Scribed by A.M.Shams El Din
- Publisher
- Elsevier Science
- Year
- 1962
- Tongue
- English
- Weight
- 256 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0013-4686
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The four acids NaH,PO,, Na2HPO,, NaPO3 and Na4P,.O7 were titrated potentiometricall), with NazO, in molten KNOs at 350°C. An oxygen electrode acted as indicator electrode, while a Ag/Ag(1) electode served as a suitable reference electrode. NaH2PO, neutralized in two steps, the second of which was id