𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Molecules with a Genuine Si—Si Triple Bond and a Stable Derivative of [SiH]+

✍ Scribed by Manfred Weidenbruch

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

HCSiF and HCSiCl: The First Detection of
HCSiF and HCSiCl: The First Detection of Molecules with Formal C≡Si Triple Bonds
✍ Miriam Karni; Yitzhak Apeloig; Detlef Schröder; Waltraud Zummack; Roberto Rabezz 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 1 views

Neutralization of [C,H,Si,X]  .+ radical cations (X=F, Cl) in conjunction with electronic structure calculations provides the first experimental evidence for the formation of the neutral silynes HC≡SiF and HC≡SiCl, which have nonlinear structures (see picture).

A theoretical study of bond energies in
A theoretical study of bond energies in model Si-H-Cl molecules using density functional approaches for representing Si surface chemistry
✍ Boehm, Randall C.; Kress, Joel D.; Martin, Richard L.; Hay, P. Jeffrey 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB 👁 2 views

The reliability of density functional theory DFT methods for calculating Si-H, Si-Cl, and Si-Si bond energies is examined in reactions involving molecules and small clusters representing various surface sites appropriate for Si surface chemistry. Results are presented for systematic studies using a