𝔖 Bobbio Scriptorium
✦   LIBER   ✦

HCSiF and HCSiCl: The First Detection of Molecules with Formal C≡Si Triple Bonds

✍ Scribed by Miriam Karni; Yitzhak Apeloig; Detlef Schröder; Waltraud Zummack; Roberto Rabezzana; Helmut Schwarz

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
137 KB
Volume
38
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

Neutralization of [C,H,Si,X]  .+ radical cations (X=F, Cl) in conjunction with electronic structure calculations provides the first experimental evidence for the formation of the neutral silynes HC≡SiF and HC≡SiCl, which have nonlinear structures (see picture).

📜 SIMILAR VOLUMES

Selective Insertion of Dioxygen into an
Selective Insertion of Dioxygen into an (η2-C60)−Ir Bond: Synthesis and Structure of the First Metallacyclic Complex with a σ-Coordinated Fullerene Molecule
✍ Alexander V. Usatov; Ekaterina V. Martynova; Fedor M. Dolgushin; Alexander S. Pe 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB

## Abstract Oxidation of the carboranyliridium fullerene complex [(η^2^‐C~60~)Ir(__o__‐HCB~10~H~9~CCH~2~PPh~2~‐__B__,__P__)(__t__BuNC)~2~] (I) in CHCl~3~ solution by O~2~ occurs by a selective insertion of the dioxygen molecule into the longest Ir−C bond (in the __trans__‐position relative to the B