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ChemInform Abstract: HCSiF and HCSiCl: The First Detection of Molecules with Formal CSi Triple Bonds.

✍ Scribed by Miriam Karni; Yitzhak Apeloig; Detlef Schroeder; Waltraud Zummack; Roberto Rabezzana; Helmut Schwarz

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199918160

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Neutralization of [C,H,Si,X] .+ radical cations (X=F, Cl) in conjunction with electronic structure calculations provides the first experimental evidence for the formation of the neutral silynes HC≡SiF and HC≡SiCl, which have nonlinear structures (see picture).

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