Molecular weights in post-polymerization of trioxan
โ Scribed by G.M. Trofimova; A.A. Berlin; G.A. Kuryukhina; I.M. Barkalov; V.I. Gol'danskii; N.S. Yenikolopyan
- Book ID
- 118358116
- Publisher
- Elsevier Science
- Year
- 1967
- Weight
- 378 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0032-3950
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The polymerization of trioxan, initiated by boron trifluoride n-butyl etherate, has been studied in cyclohexane solution at 50 ยฐ, 65 ยฐ and 70 ยฐ. Correlations have been obtained between the yields and inherent viscosities of the polymer and the main reaction variables. Increasing the concentration of
## Abstract A relatively novel method of calculating molecular weight changes and broadening during a polymerization is proposed. It differs from others in that the distribution is considered implicitly rather than explicitly. This allows direct use of kinetic rate equations in the derivation of we