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Molecular Weight and Branching Distribution Modeling in Radical Polymerization with Transfer to Polymer and Scission Under Gel Conditions and Allowing for Multiradicals

✍ Scribed by Yaghini, Nazila; Iedema, Piet D.

Book ID: 125808449
Publisher: American Chemical Society
Year: 2014
Tongue: English
Weight: 676 KB
Volume: 47
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma501094a

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Dependencies of PDI on monomer conversion (a = ([M] 0 -[M])/[M] 0 ) for systems with [M] 0 /[I] 0 = 10 2 , computed for various (shown in the Figure) values of (k tr / k p ) N ([M] 0 /[I] 0 ). Dotted lines: systems without disproportionation (Ref. [1] ), circles: systems with disproportionation.