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Molecular Transformations of Unsaturated Thiacrown Ethers

✍ Scribed by Tsuchiya, Takahiro; Okada, Yosuke; Shimizu, Toshio; Hirabayashi, Kazunori; Kamigata, Nobumasa

Book ID: 126787374
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 178 KB
Volume: 73
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo701757s

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## Abstract Partially unsaturated 14‐ and 28‐membered thiacrown ethers, **3** and **4**, which possess alternating Z‐carbon‐‐carbon double bonds and propylene chains, were synthesized by stepwise reactions. The crystal structure of larger cyclic compound **4** was determined by X‐ray crystallograph