Molecular theory of solvation processes in dipolar and non-dipolar solvents
โ Scribed by Harold L. Friedman; Fernando O. Raineri; Baw-Ching Perng; Marshall D. Newton
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 921 KB
- Volume
- 65-66
- Category
- Article
- ISSN
- 0167-7322
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
AImtract--Centro-symmetric molecules such as anthracene and its 9,10-disubstituted derivatives often show solvatochromic shifts of their absorption and fluorescence spectra in a series of solvents of different static dielectric constants. These shifts have been explained by the existence of small di
On the basis of previous rc.41~ lor molecular association studied in aprotic dipolnr solvents by the non-lnear dielectric ekct (NDE) it has been shown thal in the case or associaion due 10 dipolar imrracGons\_ we can apply the same inwrpremGon or NDE as for strong hydrogen-bonded and charge-wanskr c
The excess dielectric polarization and the dipolar excess heat of mixing for systems of propan-Z-01, butan-l-01, 3 methyl butan-l-01 and phenyl carbinol + nonpolar solvents like cyclohexane, carbon tetrachloride and benzene were studied by the measurements of refractive indices and dielectric consta