A microscopic theory is described for the ion solvation dynamics in binary dipolar liquids. The theory is self-contained and properly includes inertial and non-Markovian effects which are extremely important in the fast initial phase of the relaxation. The theory also includes diffusional effects im
Microscopic theory of solvation of an ion in a binary dipolar liquid
โ Scribed by A. Chandra; B. Bagchi
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 1023 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0167-7322
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๐ SIMILAR VOLUMES
Theoretical expressions for the time-dependent salvation energy of an ion and of a dipole in a dense dipolar liquid are derived from microscopic considerations. We show that in contradiction to the prediction of the continuum models, the dynamics of these two species are significantly different from
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