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Molecular tectonics V: Molecular recognition in the formation of molecular networks based on hydrogen bonding and electrostatic interactions

✍ Scribed by Olivier Félix; Mir Wais Hosseini; AndréDe Cian; Jean Fischer


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
264 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


The formation of (x-molecular networks based on dihapto mode of H-bonding was investigated in the solid state using bis-cyclic amidinium dications and acetylenedicarboxylate dianion. It has been demonstrated that the formation of networks depends strongly on the structure of the components. A proper disposition of H-bond donor and acceptor sites indeed leads to the formation of infinite molecular assemblies in the crystalline phase.


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