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Molecular tectonics IV: Molecular networks based on hydrogen bonding and electrostatic interactions

✍ Scribed by Olivier Félix; Mir Wais Hosseini; André De Cian; Jean Fischer

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
249 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Whereas diprotonated 1 (1,2-Bis(2'-tetrahydropyrimidyl)ethane) forms a discrete exobinuclear complex with a dihapto mode of hydrogen bonding with 4-methylbenzoate anion 2" in the solid state, with 4,4'-biphenyldiearboxylate 32-an or-network composed of 1-2H + dieation and 32-dianion interconnected through strong hydrogen bonds and arranged in an alternating manner was obtained. The interconnection of the linear chains by water molecules affords a I~-network.

📜 SIMILAR VOLUMES

Molecular tectonics V: Molecular recogni
Molecular tectonics V: Molecular recognition in the formation of molecular networks based on hydrogen bonding and electrostatic interactions
✍ Olivier Félix; Mir Wais Hosseini; AndréDe Cian; Jean Fischer 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 264 KB

The formation of (x-molecular networks based on dihapto mode of H-bonding was investigated in the solid state using bis-cyclic amidinium dications and acetylenedicarboxylate dianion. It has been demonstrated that the formation of networks depends strongly on the structure of the components. A proper