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Molecular tectonics: design and structural analysis of 1-D and 2-D self-inclusion molecular networks in the crystalline state

✍ Scribed by Julien Martz; Ernest Graf; Mir Wais Hosseini; André De Cian; Nathalie Kyritsakas-Gruber

Publisher: Elsevier Science
Year: 2002
Tongue: English
Weight: 279 KB
Volume: 5
Category: Article
ISSN: 1631-0748
DOI: 10.1016/s1631-0748(02)01393-0

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✦ Synopsis

The synthesis of the new symmetrical koiland 2 based on the double fusion of two p-ethylcalix [4]arene in cone conformation by two silicon atoms was achieved and its structure confirmed by X-ray diffraction on a single crystal. Koiland 2, a concave building block possessing two calix-type pre-organised cavities disposed in a divergent fashion as well as ethyl groups as potential connector moieties, affords either a discrete exo-binuclear inclusion complex in the solid state in the presence of p-xylene acting as a stopper or infinite 1-D or 2-D self-inclusion networks or koilates, mainly based on van der Waals interactions and resulting from the inclusion processes taking place between concave and convex moieties of consecutive koilands.

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