Molecular structures and thermodynamic functions of 2-methylbutane and 2,3-dimethylbutane
β Scribed by Boyd, Richard H.
- Book ID
- 127091744
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 584 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The microwave rotational spectrum of 2-methylbutane has been measured and assigned to two conformers with C s and C 1 symmetry. Similarly, the rotational spectrum of the C 2 conformer of 2,3-dimethylbutane has been observed, assigned, and analyzed. Its C 2h conformer, undoubtedly present, is nonpola
Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info