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Molecular Structures and Electronic Transitions of 3,6-Diphenyl-1,2-dithiin and Its Radical Cation: A Spectroelectrochemical and DFT Study

✍ Scribed by Hennig, Horst; Schumer, Frank; Reinhold, Joachim; Kaden, Heiner; Oelssner, Wolfram; Schroth, Werner; Spitzner, Roland; Hartl, František


Book ID
115538481
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
165 KB
Volume
110
Category
Article
ISSN
1089-5639

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✍ A. M. Nesterenko; N. I. Buryak; O. M. Polumbrik; A. A. Yasnikov 📂 Article 📅 1988 🏛 Springer US 🌐 English ⚖ 500 KB

large strong-field increment for 2-CH~ was observed here, and the chemical shift for this carbon atom is 14.5 ppm, whereas it was more than 19.8 ppm in all other cases. A "~ effect" in this case is clearly observed not only for C(s ) but also for C(~) and C(6 ) (Table 3). The substantial dependence