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Molecular and electronic structures of radical-cations derived from diphosphines: a semi-empirical PM3 study

✍ Scribed by Christopher Glidewell

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
487 KB
Volume
409
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES

Studies on Radical Cations I. Molecular
Studies on Radical Cations I. Molecular and electronic structure of [3]radialene cation produced by Ξ³-irradiation in condensed phase
✍ Thomas Bally; Edwin Haselbach; Zuzana Lanyiova; Peter Baertschi πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 780 KB

## Abstract γ‐Irradiation of tris (methylidene)‐cyclopropane (β€˜[3]radialene’) **1** in a rigid electron scavenging matrix (butylchoride/i‐pentane, 1:1) at 77 K leads to formation of its molecular cation **1**^+^. Slight softening of the matrix by a temperature increase of 3–5 K results in formation