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Molecular structure of .mu.-diazido-tetrakis(triphenylphosphine)dicopper(I)

✍ Scribed by Ziolo, Ronald F.; Gaughan, Arthur P.; Dori, Zvi.; Pierpont, Cortlandt G.; Eisenberg, Richard.


Book ID
127315438
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
255 KB
Volume
92
Category
Article
ISSN
0002-7863

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✍ Bessler, Karl E. ;Calzavara, Leandro A. de P. ;Deflon, Victor M. ;Niquet, Elke 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

Colourless crystals of the title compound, [Cu 2 (C 4 N 3 ) 2 -(C 18 H 15 P) 4 ], were obtained by the reaction of CuC(CN) 3 with excess of molten PPh 3 . The crystal structure contains centrosymmetric dimeric units bridged by two C(CN) 3 ligands. The Cu atoms have a distorted tetrahedral coordinati