Diels-Alder reactions / 1,2-Dicyano-1,3-~yclobutadiene / Dewar benzenes / High-pressure reactions The trimerization of cyanoacetylene (la) and the Diels-Alder reaction of l a with 1,3-cyclohexadiene (2) show a powerful pressure-induced acceleration which allows the reaction temperature to be reduce
✦ LIBER ✦
Molecular structure of hexafluorobicyclo [2.2.0]hexa-2,5-diene (hexafluoro-dewar-benzene) in the vapour phase
✍ Scribed by Bjørn Ahlquist; Birgit Andersen; Hans M. Seip
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 570 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-2860
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According to the observations and data reported by Willstutter and Wuser [4], rather pure COT may have been obtained in their first attempt to synthesize this compound. Note also that independent from Cope and Hochstein [l], Ziegler and Wilms [3b] carefully separated the products obtained by reducti