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Molecular structure of (E)- and (Z)-methylcyanovinyl sulphone in the gas phase and in crystal

✍ Scribed by E. Vajda; D. Hnyk; B. Rozsondai; J. Podlaha; J. Podlahová; J. Hašek


Book ID
107803230
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
758 KB
Volume
239
Category
Article
ISSN
0022-2860

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A straightforward preparation has been found for bis(dichlorosilyl)methylamine, (SiHCl 2 ) 2 NMe (1), involving reaction between H 2 NMe and an excess of SiHCl 3 , dissolved either in pentane or THF at 253 K. 1 and a side-product, 1,3,5-trichloro-2,4,6-trimethylcyclotrisilazane, (±SiHCl±NMe±) 3 (2),