Chlorobis(pentafluoroethyl)phosphane: Improved Synthesis and Molecular Structure in the Gas Phase
✍ Scribed by Dr. Stuart A. Hayes; Dr. Raphael J. F. Berger; Prof. Dr. Norbert W. Mitzel; Dr. Julia Bader; Prof. Dr. Berthold Hoge
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 366 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
A straightforward preparation has been found for bis(dichlorosilyl)methylamine, (SiHCl 2 ) 2 NMe (1), involving reaction between H 2 NMe and an excess of SiHCl 3 , dissolved either in pentane or THF at 253 K. 1 and a side-product, 1,3,5-trichloro-2,4,6-trimethylcyclotrisilazane, (±SiHCl±NMe±) 3 (2),
Reactions of dialkyl(trimethylsilyl)phosphanes RRЈPSiMe 3 (1: compounds R 3 SnSiCl 3 (19a-c) that decompose providing (R 3 Sn) 2 Si(SiCl 3 ) 2 (18a-c) and nBu 3 SnSi(SiCl 3 ) 3 (20c). R, RЈ = tBu; 3: R, RЈ = iPr; 5: R = iPr, RЈ = tBu) with Si 2 Cl 6 provide stable trichlorosilylphosphanes RRЈPSiCl 3