The molecular structure of trimethyl(methylene)phosphorane, (CHJJP= CH2, in the gas phase has been determined by electron diffraction. Principal distances are r,(P -C) = 181.5(3), ra(P = C) = 164.0(6) pm; and the angles between the P-C(methy1) bonds are lOl.qSY. These parameters lead to a value for
A new synthesis and the molecular structure of trimethyl(silylmethylene)phosphorane in the gas phase, determined by electron diffraction
β Scribed by Ebsworth, E. A. V. ;Rankin, David W. H. ;Zimmer-Gasser, Beate ;Schmidbaur, Hubert
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1980
- Tongue
- English
- Weight
- 448 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0009-2940
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Reactions of dialkyl(trimethylsilyl)phosphanes RRΠPSiMe 3 (1: compounds R 3 SnSiCl 3 (19a-c) that decompose providing (R 3 Sn) 2 Si(SiCl 3 ) 2 (18a-c) and nBu 3 SnSi(SiCl 3 ) 3 (20c). R, RΠ = tBu; 3: R, RΠ = iPr; 5: R = iPr, RΠ = tBu) with Si 2 Cl 6 provide stable trichlorosilylphosphanes RRΠPSiCl 3