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An Electron Diffraction Determination of the Molecular Structure of Hexamethylcarbodiphosphorane in the Gas Phase

✍ Scribed by Ebsworth, E. A. V. ;Fraser, Thomas E. ;Rankin, David W. H. ;Gasser, Oswald ;Schmidbaur, Hubert


Publisher
Wiley (John Wiley & Sons)
Year
1977
Tongue
English
Weight
421 KB
Volume
110
Category
Article
ISSN
0009-2940

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The Molecular Structure of Trimethyl(met
✍ Ebsworth, E. A. V. ;Fraser, Thomas E. ;Rankin, David W. H. πŸ“‚ Article πŸ“… 1977 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 288 KB

The molecular structure of trimethyl(methylene)phosphorane, (CHJJP= CH2, in the gas phase has been determined by electron diffraction. Principal distances are r,(P -C) = 181.5(3), ra(P = C) = 164.0(6) pm; and the angles between the P-C(methy1) bonds are lOl.qSY. These parameters lead to a value for