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Molecular Structure and Cluster Formation of a tert-Butylborylene Complex

✍ Scribed by Holger Braunschweig; Christian Burschka; Michael Burzler; Stephanie Metz; Krzysztof Radacki


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
178 KB
Volume
45
Category
Article
ISSN
0044-8249

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N 3 P 3 Cl 6 reacts with 2-(aminomethyl)pyridine under formation of the stable geminal difunctionalized compound gem-N 3 P 3 Cl 4 (NHCH 2 (C 5 H 4 N)-2) 2 1. The chlorine atoms can be substituted by reacting 1 with sodium phenoxide to yield gem-N 3 P 3 (OC 6 H 5 ) 4 (NHCH 2 (C 5 H 4 N)-2) 2 2. A vic