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Molecular Recognition by Cyclic Urea Mimetics of α-Chymotrypsin

✍ Scribed by CAROL A. VENANZI; JEFFREY D. BUNCE


Book ID
118724117
Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
157 KB
Volume
471
Category
Article
ISSN
0890-6564

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Porphyrin dimer linked with chiral binaphthyl derivative was prepared as a ditopic eoreceptor for a series of diamines. Its zinc complex shows the good affinity for ct,o~-diamines H2N(CH2)nNH2 (n = 6, 8, 10, 12; Ka = 105 -106 M -1 in CH2C12 at 15 °C). These complexes gave the significant bisignate C