✦ LIBER ✦

Molecular polarizability and bond polarizability derivatives of benzyl chloride and benzyl bromide

✍ Scribed by V. Kumar; U.P. Verma; A.N. Pandey

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 212 KB
Volume: 56
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)89043-5

No coin nor oath required. For personal study only.

✦ Synopsis

The delta function potential model of chemical binding has been employed to compute the bond and molecular polarizabilities of benzyl chloride and benzyl bromide. The transferabdity of bond parallel component has been examined. The semiempirical equations proposed by Long and Plane, and Lippincott and Nagarajan have been employed to evaluate bond polarizabiiity derivatives and compared with experimental values. It has been found that for bonds to hydrogen and halogen the Long and Plane equation gives satisfactory results, whereas for carbon-carbon single and multiple bonds the equation of Lippincott ard Nagarajan is most suitable_

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