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Molecular photoelectron spectroscopic investigation of some caged phosphorus compounds and related acyclic species

✍ Scribed by Cowley, A. H.; Goodman, D. W.; Kuebler, N. A.; Sanchez, M.; Verkade, J. G.

Book ID
127076599
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
822 KB
Volume
16
Category
Article
ISSN
0020-1669

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The different reactivity of P,[Si(CH,),], (1) and P7(CH3), (2) is discussed in terms of a simple MO scheme. This scheme is based on semiempirical calculations (MIND0/3, MNDO) and on He(1) photoelectron spectroscopic investigations on 1 and 2. The electronic structure of similar cage compounds with t